Give
me the simplest form of
matter
and motion,
and I will build, out of them, the world
of Nature.
"Give me matter,
and I will construct a world out of it."
Immanuel
Kant, Kant's Cosmology
("Universal
Natural History and Theory Of
Heavens")
13.
Chemical Element Classification
(Chemclass)
In
the previous page, we began classifying the
chemical elements (chemels)
trough their various properties. The most
general chemel
classification (chemclass) is that a
chemel
can be either stable or
unstable.
A
stable chemel (stachem) can further be
classified as being either active or
inactive.
Due
to the preservation
tendency mark of creation (PT-UMOC),
to preserve their stability,
stachems
must be endowed, from their birth, with a
locking mechanism that could be called a
chemical lock (chemlock).
The
"active"
stable chemels are characterized
by being open to combine, when in
contact with other chemels, into
various aggregates or formations,
called chemical composites
(chemcomps), that appear to exert
an aura of saturation and
completeness (sac).
.The
"inactive"
stable chemels, on the other
hand, seem to be locked in a dormant,
non-reactive state, when in contact
with other chemels, appearing of
displaying an aura of being already
saturated and complete
(sac).
.That
saturation
and completeness
(sac)characteristic, that appears to
exist and be central to all
chemelscaught
our attention in a most profound way,
leading us to recognize
The
Seventeen
Foundational
Universal Recognition Of
Nature
(17thFURON): The
Universal Principle Of Saturation
(TUPOS)
All
matter has the natural
tendency to become and stay
saturated.
The
saturated
matter
(satma)
is a "closed-in" substance that is
inactive and "complete" while
the unsaturated matter, called
active
matter
(actma),is
a substance that is active and
"incomplete", being open to combine
with other chemels
to form new stable "saturated"
combined
entities. (If those combined entities are
made of the same
chemels,
they are called
molecules;
if not, they are called
compounds.)
Thus,
for instance, through the
combination of two (2)
Oxygen-chemels, we get the
Oxygen (O2)
moleculewhile through the
combination of two (2)
Hydrogen-chemels with one (1)
Oxygen-chemel, we get the
Water (H2O)
compound.
!
Remark:
It
is important to recognize that
TUPOS
exists because of
Downlev
--the ultimate physical law of
Nature (Uplon)
detailed as follows:
i)Actma
is fueled by the
ergolevelingprocess
dictated by
Downlevand
ii)Satmais protected by
Downlev
through its
objective
of
existence
of not allowing any
permanent
deviation from its
stable state of
existence. That
protective reach of
Downlev
is
an outreach of the
preservation
tendency mark of
creation
(PT-UMOC).
Definitions:
A saturated
chemel(chemSAT) is a chemel
that exists in a closed,
unresponsive state, that stays
unaffected by being in contact
with any other chemels,
reflecting as such, an aura of
saturation and completeness
(sac).
(By
"saturated",
in this context, is
meant of a chemel not
accepting any more
electrons.)
Remark:
There
is no guaranty, of
course, that a
chemel
in contact with a
chemSAT
is not being able to
"steal" electrons
from it, to form in
the end, a
compound
with it. For that to
happen, the
pirate
chemel (pirac)
must somehow be
able to break the
chemSAT's
chemlock.
An active
chemel(chemACT) is a chemel
that exists in an open state,
ready to react and interlock
with some other contacting
chemels, to form a
"saturated"chemcomp.
Thus,
we can talk about the two
kinds of stachemsthat exist in Nature:
the unresponsive
ChemSATsand, the
responsiveChemACTs.
Both those types of
stachems
exist because of
Downlev.
With that stachemclassification
behind us, we now continue by examining their
presence, if any, in the Periodic Table
of Chemels
(PETAC).
Are
There Any ChemSAT in the Periodic Table of
Chemels (PETAC)?
From
various experimental data, it was gradually
recognized that the
Helium
group,
called the noble gases (nobgas) group,
appeared to be the only group that did not react
or combine when it was placed in contact with
other chemels.
Because of that non-reactivity towards other
chemels
when in contact, it was reasoned that the
nobgas
group was comprised of chemels that were somehow
"full," "complete," or "saturated."
WHAT
then,
those chemels of the nobgas
group had in common, that set them apart, and
made them unreactive or unresponsive towards
other chemels in
contact?
Upon
the introduction of Niels Bohr's
planetary structural model of the atom (now,
abolished), it was reasoned that the outer
"planetary" electrons, and only them, were the
ones involved in a chemical reaction
(chemrec).
As
such,
it was further reasoned that the outer ring
(oring) of electrons must hold the key as to
WHY the chemels
of the nobgas
group stay neutral towards other
chemels
in contact. Thus, it was conjectured that if the
oring
is packed to its fullest capacity, i.e., being
saturated, then those saturated orings
(sators) hold the ticket to their
neutrality.
With
that understanding, that all orings
of nobgases
are saturated
(being, as such, sators),
the next logical question, that would have
required an answer for the study of the
sators
of
nobgases,
would have been perhaps this one, regarding
their sizes: WERE
those satorsof the same size for each chemel
of nobgases,
or do they differ for each member of the
nobgas
group, and thus differ in their packing
capacity?
That question which was never asked, much less
answered, can be answered in here through:
The Packing Corollary Of Sators
(PACOS)
The
packing capacity of a
sator
is not function of its
size.
Proof:
This
is a direct result springing from
TELSAT.
Regardless of their sizes, all
sators
from the nobgas
group will contain the same maximum
finite (Maxfin) number of packed
electrons.
QED.
WHAT
then that maximum
finite (Maxfin)
number of packed electrons is for a
sator
of the nobgas
group?
Well,
the answer to that, most certainly, could not
come from the blueprint of TRUTON presented
herein. And that is because that question is not
answerable here no more than answering WHY the
number
82(and no other number) is the
Maxfin
number of protons that a NUC
must have in order for its chemel
to say nonradioactive.
The natural
radioactivity (narad)
begins indeed with the
chemel 83
in PETAC
that is the Bismuth
(83Bi).
In short, Maxfin
82
corresponding to Lead
(82Pb),
is not a result emerging from TRUTON, but is one
resulted from the experimental data
(experda).
As
such,
that sought Maxfinanswer
for the nobgas
group must come from some other place,
specifically from conjectures derived from the
study of chemical
reactions (chemrecs).
Richard Abegg
In 1904, Richard Abegg, experimenting
with the combining properties of
Sulfur (16S), noticed
that when combined with the
Hydrogen (1H) in
obtaining the
Hydrogen Sulfite (H2S)
--Sulfur
exhibited a lost of two (-2)
electrons, but when combined with
Oxygen (8O) and the
Hydrogen (1H) in
obtaining Sulfuric Acid
(H2SO4) --
Sulfur
gained six (+6) electrons:
two (+2) from the
Hydrogen
and four (+4) from the
Oxygen.
As such, the combined absolute range of
the Sulfur
from the
minus 2
to the plus 6
of the two performed chemrecs
amounted to the range sum of
eight (8).
Gilbert
N. Lewis
Irving
Langmuir
Stunningly from
there,
Abegg
extrapolated that finding with the
Sulfur,
for all chemels!
The
empirical embryonal "Octet Rule" was born
now in several stages.
First,
with that extrapolation, the so-called "Rule
of Eight" was born. Then, in 1916, that
empirical rule was picked up by Gilbert N.
Lewis in his seminal cubic atom theory
calling it, for the first time, the "Abegg's
Rule." From there, in 1919, Irving
Langmuir, developed his own empirical
"octet theory" that eventually become
cemented as the "Octet Rule."
Through
the "Octet
Rule"
conjecture, the nobgas
group was now understood to have in their
orings
that saturated
value of eight
(8)
electrons that represented the Maxfin
number.
The
number of electrons that a ChemACT
needs to have for reaching the Octet Ruleformation
for its oring
or ovalonis
called its valence. Thus, the valence
number (valnu) is a whole number without a
sign and, as such, from
valnu,
we cannot have any indication whether the
ChemACT
has gained (+) or lost (-) electrons
in its oring
(ovalon)during
its interaction with other chemel. The range of
valnu
is, as such, from 1 to 7, since 8 is a complete
octet.
That
limitation with the
valnu
representation has been eliminated with the
introduction of the oxidation number
(oxinum) that is a number that keeps track
of the electrons in the oring
(ovalon)
of the chemel and incorporates, as such, both
signs:
with
the negative (-) sign when there is a
gain of the (negative) electrons
and, with the positive (+) sign when
there is a lost.
Remarks:
(1-7) . . . (±)
1.
In the modern language of Chemistry, the
Abegg's
Rule
can be expressed through the concept of
valence
and expanded into the oxidationstate
concept that, as noted, differentiate an atom
that is an electron grabber that gains
electrons (negative valence) from the one,
that is an electron loser by losing electrons
(positive valence). 2.
In the TRUTON lingo, we note that the
oring
is the ovalon
and, that the saturated
oring (sator)
is the saturated
ovalon (satov).
The
Octet Rule
conjecture has been paramount for providing the
general blueprint of how ChemACTs
will react towards other like chemels: that of
getting a saturated 8-electron pack into their
outer ring --the oring
(i.e., into their ovalon),
i.e., that of getting a satovmodulo
the Octet Rule.
The
combining capacity of a
ChemSAT
is therefore (as recognized through the
blueprint paved by the Octet Rule)
a function of the numbers of the outer
electrons, called valence electrons
(valELs), that were needed for its
ovalon
to became saturated i.e., to become a
satov.
That combining capacity led, as noted, to the
concept of valence
that was created to show how a chemical bond
(chembond) is being formed.
That
ChemACTs
can unite in creating a chembondthrough
their outer valELs
of their respective ovalons,
led to the recognition that their unification
can be achieved through two, and only two,
distinct pathways:
either
through a sharing or
trough a capture of the outer
valELs,
creating, as such,
either
a covalent bond(coB)
or a ionicbond
(ioB), respectively
Polar Covalent (poco)
Bonds
By the concomitant influences supplied
by two uniting ChemACTson
their commonly shared
valence
electrons (valELs),
energy (as in a pull) is going to be
released that will be used in cementing
the stability of the chembond.
However,
differentChemACTs
will attract the shared valence
electrons (valELs)
with different forces. As such,
there is an inequality in the amount of
the "pull" exerted on its valence
electrons valELs
by the various chemels.
Those
(valELs),
as such, will experience pulls of
various degree of intensity. Thus, to
each participating
chemel,
we can associate a measurement for its
tendency to grab or to pull those
valELs.
If
we call electronegativity
(ELneg), the measurement of a
chemel's
strength of that tendency to grab or to
pull a valence electron
(valELs),
then (as recognized and developed in
the valence bond theory by
Linus Pauling) due to that pull
inequality, we can talk about
chemels
of highELneg
(such as Fluoride, Oxigen, Nitrogen, or
Chlorine) or of lowELneg
(such as the alkali metals or the
alkaline earth metals).
All
this recognition of different levels of
ELneg
leads to the unequal sharing of valence
electrons (valELs)
between chemels,
as valELs
will be drawn closer to
chemels
of higher ELneg.
A
large difference in ELneg
of its partnering bonding
chemels,
leads to a stronger polar
(ionic) character of the bond.
The
higher the value of the
ELneg
of a
chemel
is, the more strongly that
chemel
attracts the shared valence
electrons (valELs).
As
such,
chemels
with the highest
ELnegwill
be the prime candidates and
suspects to become
"pirate"
chemelc (piracs)
when
facing the nobgas
group.
In
fact, in 1933,
Linus
Pauling
predicted such a scenario with
Fluoride
and
Oxygen
as being the
front-runners.
Those predictions,
such as with Krypton
Hexaflouride
(KrF6) or
with Xenon
Hexaflouride
(XeF6)
were proved to be
accurate, indeed.
And
1962,
Neil Bartlett,
was the first to
report of the highly
oxidizing compound
Platinum Hexafluoride
(PtF6). He
also reported, in the
same year, of
obtaining the
synthesized Xenon
Tetrafluoride
(XeF4) by
exposing a mixture of
Xenon (Xe) with
Fluorine (F) to a
high temperature.
After
that,
the gate was quite
open in discovering a
plethora of
additional
nobgases
compounds. The
nobgas
group has lost, as
such, its "inert"
title,
irreversibly.
And speaking of gate opening, we may
want to note this:
Soon
after the introduction of the empirical
Octet
Rulecemented
in 1919 by IrvingLangmuir,
it was recognized that with that rule,
it cannot be explained other
chemrecs
with other chemels
from PETAC.
As such, two years later, in 1921,
Langmuir
introduced another empirical rule --the
18-electron rule that was able
to explain partially chemrecs
involving the stable transition of
metal complexes. Once that gate with
the empirical rules was wide open, a
flood of empirical rules followed with
no end in sight.
With that,
Chemistry has entered now into
its murky zone. The Murky Zone of
Chemistry (Muzoc) was
born...
Linus
Pauling
With that succinct and incomplete presentation
of the covalent
bonds (coBs),
we now tend to move towards the other type of
chembonds:
one,
at the ionic bonds type
On Ionic Bonds(ioBs)
Ionic bonds (IoBs) were defined as chemical
bonds (chembonds)
where their valence
electrons (valELs)
are being transferred (as opposed to being
shared). However, during those transfers, the
electrons inevitably will be subject to the
influence of the two atoms that are being
engaged with and, as such, those transferred
electrons would encounter a certain degree of a
covalent
bond (coB),
as well. Thus, "pure"
ioBs
do not really exist in Nature as some sharing,
and thus some degree of
covalent
bond (coB),
will always exist.
Because
of that blurring overlap of the two types of
bonds, we can talk about the
covalent
and the ioniccharacter of the bond. For a
bondto
be ionic(ioB),
the ionic
character
must be the dominant one and reflected in the
difference of electronegativity
(ELneg)
that exist between the two participating
chemels.
That is to say, that a
ionic
bond (ioB)
must be more polar
(ionic)
than in a covalent
bonding (coB)
where electrons are being shared more
equally.
and the
other,
at the metal bonds type
On
Metallic Bonding(Meb)
Looking at the Periodic
Table (PETAC)
of the chemical elements (chemels),
we note that the majority of them are metals.
There, in the metal world, each chemel releases
one or more of its electrons creating
collectively a common "cloud" arena of electrons
that resides between them. That common ground
"cloud" arena is made from the individual
mini-clouds "parcels" that each electron is
bringing with it through its carrying
XB-cloud.
Due
to the lost of those electrons, those
metal-chemels become now positively charged. The
generated "cloud" arena of "liberated" electrons
are now being attracted by a multitude of
chemels without being part of any of them. A
collective common bonding (of the participating
chemels) is being formed that is the called
metallic bonding (meb). The common cloud
of electrons, characteristic in a metallic
bonding, is responsible indeed for their good
electrical and thermal properties.
Much, much more, needs to be added in here for
the stable
chemels (staches),
but now we move on to the other major type of
chemical elements (chemels)
--the unstable ones.
The unstable chemels are the
radioactive chemels (radchems) whose
Maxfin
number is greater than 82
as noted above. This subject of the
radioactivity
has been presented, in brief, in the
page 10, and it will not be expanded in
here. With this, we are leaving not only this
page, but are leaving this entire section.
Before moving to the last section of TRUTON, the
Evolutionary Biology
section,
we present next a brief outlook of TRUTON:
Present and Future.
.